Open Access Article

Investigation on Ficus carica and Punica granatum Extracts as Eco-Friendly Corrosion Inhibitors for C1018 Carbon Steel in Acidic and Marine Environments

Authors

  • Abdlmanam S. A. Elmaryami

    Department of Mechanical Engineering, Faculty of Technical Engineering, Bright Star University (BSU), El-Brega P.O. Box 858, Libya

  • Omar Nashed

    Applied Chemistry Department, Faculty of Applied Science, Maaref University of Applied Sciences, Sarmada, Syria

  • Mahmoulah Y. Abdulraheem

    Department of Chemical Engineering, Faculty of Technical Engineering, Bright Star University (BSU), El-Brega P.O. Box 858, Libya

  • Abdul Hamid Omran Saleh

    The Corrosion Protection Department, Sirt Oil and Gas Production and Manufacturing Company, El-Brega P.O. Box 385, Libya

  • Salah Mohamed Sallab

    The Corrosion Protection Department, Sirt Oil and Gas Production and Manufacturing Company, El-Brega P.O. Box 385, Libya

  • Garrett Arciete

    The Corrosion Protection Department, Sirt Oil and Gas Production and Manufacturing Company, El-Brega P.O. Box 385, Libya

  • Rahel G. Rahel

    Department of Chemical Engineering, Faculty of Technical Engineering, Bright Star University (BSU), El-Brega P.O. Box 858, Libya

DOI:

https://doi.org/10.55121/nefm.v5i1.1249
Received: 3 March 2026 | Revised: 17 April 2026 | Accepted: 24 April 2026 | Published Online: 1 May 2026

Abstract

This study evaluates the corrosion behavior of carbon steel in acidic medium and seawater in the presence of natural plant extracts derived from pomegranate peels and fig leaves as environmentally friendly corrosion inhibitors. The weight loss technique was employed to determine the corrosion rate and inhibition efficiency after an immersion period of 624 h, in the absence and presence of different inhibitor concentrations ranging from 12.5 to 100 ppm. The results demonstrated that pomegranate peels and fig leaves extracts were ineffective in the acidic medium, as negative inhibition efficiency values were recorded, indicating an increase in the corrosion rate compared to the blank solution. In contrast, the extracts exhibited noticeable corrosion inhibition performance in seawater, where positive inhibition efficiency values were observed and improved with increasing inhibitor concentration. Fig leaves extract showed superior performance, achieving a maximum inhibition efficiency of approximately 27.47% at a concentration of 100 ppm. This improvement is mainly attributed to the adsorption of organic compounds present in the extracts onto the steel surface. resulting in the formation of a protective film that reduces metal dissolution in the marine environment. The findings of this study indicate that pomegranate peels and fig leaves extracts are ineffective under the studied conditions in acidic environments but demonstrate promising potential as eco-friendly inhibitors in marine or saline conditions. These results highlight the critical influence of the corrosive medium on inhibitor performance and support the use of natural plant extracts as sustainable alternatives to conventional chemical inhibitors of corrosion.

Keywords

Ficus carica, Punica granatum, Green Inhibitors, Fig Leaf Extract, Pomegranate Leaf Extract, Corrosion Inhibition Rate, Corrosion Inhibition Efficiency

References

[1] Maaß, P., 2011. Corrosion and Corrosion Protection. In: Maaß, P., Peißker, P. (Eds.). Handbook of Hot-Dip Galvanization. Wiley-VCH: Weinheim, Germany. pp. 1–19. DOI: https://doi.org/10.1002/9783527636884.ch1

[2] Redkina, G.V., Sergienko, A.S., Kuznetsov, Y.I., et al., 2020. Hydrophobic and Anticorrosion Properties of Thin Phosphonate-Siloxane Films Formed on a Laser Textured Zinc Surface. International Journal of Corrosion and Scale Inhibition. 9(4), 1550–1563. DOI: https://doi.org/10.17675/2305-6894-2020-9-4-23

[3] Biryukov, A.I., Kozaderov, O.A., Galin, R.G., et al., 2020. Details of the Mechanism of Dissolution of Iron-Zinc Coatings Based on the δ-Phase in Acidic Media. International Journal of Corrosion and Scale Inhibition. 9(4), 1477–1489. DOI: https://doi.org/10.17675/2305-6894-2020-9-4-18

[4] Kuznetsov, Y.I., 2020. Triazoles as a Class of Multifunctional Corrosion Inhibitors. Review. Part II. 1,2,3-Benzotriazole and Its Derivatives. Iron and Steels. International Journal of Corrosion and Scale Inhibition. 9(3), 780–811. DOI: https://doi.org/10.17675/2305-6894-2020-9-3-1

[5] Jawad, R.S., Kadhim, A., Fayadh, S.M., et al., 2016. Improvement of the Fatigue Resistance and Increase Its Life of Specimens of Naval Brass Alloy Using Laser Shock Wave Processing. Journal of Nanoscience and Technology. 2(1), 69–72.

[6] Agi, A., Junin, R., Rasol, M., et al., 2018. Treated Rhizophora mucronata Tannin as a Corrosion Inhibitor in Chloride Solution. PLoS One. 13(8), e0200595.

[7] Sithuba, T., Murulana, L.C., 2025. Study on the Corrosion Inhibition Effects of Flavonoid Derivatives on Aluminium in Hydrochloric Acid. International Journal of Electrochemical Science. 20(11), 101171.

[8] Al-Amiery, A.A., Kadhum, A.A.H., Mohamad, A.B., et al., 2013. Electrochemical Study on Newly Synthesized Chlorocurcumin as an Inhibitor for Mild Steel Corrosion in Hydrochloric Acid. Materials. 6(12), 5466–5477. DOI: https://doi.org/10.3390/ma6125466

[9] Al-Amiery, A.A., Kadhum, A.A.H., Mohamad, A.B., et al., 2013. A Novel Hydrazinecarbothioamide as a Potential Corrosion Inhibitor for Mild Steel in HCl. Materials. 6(4), 1420–1431. DOI: https://doi.org/10.3390/ma6041420

[10] Elmaryami, A.S., Abdullah, A.A., Mohammed, M.A., et al., 2025. An Evaluation of Wood Ashes as an Eco-Friendly Environmentally Corrosion Inhibitor for Low Carbon Steel in Acidic Solution at Different Temperatures. Zastita Materijala. 66(2), 412–420. DOI: https://doi.org/10.62638/ZasMat1236

[11] Elmaryami, A.S.A., Nashed, O., Abdulraheem, M.Y., et al., 2025. An Overview on the Corrosion Inhibitors Extracted from Natural Products. European Modern Studies Journal. 9(2), 174–187. DOI: https://doi.org/10.59573/emsj.9(2).2025.14

[12] Krishnanjana, K., Ganesh, G.M., 2026. Efficacy of Punica granatum Peel Extract on Thermo Mechanically Treated Steel Bar Corrosion through Electrochemical Noise Analysis. Results in Surfaces and Interfaces. 23, 100766. DOI: https://doi.org/10.1016/j.rsurfi.2026.100766

[13] Rahmouni, H., Nigri, S., Nacef, M., et al., 2024. Analysis of Fig Leaf Extract as Steel Eco-Friendly Corrosion Inhibitor in Acidic Medium: Electrochemical, Gravimetric, Spectroscopic, and Surface Studies. Analytical & Bioanalytical Electrochemistry. 16(2), 142–162. DOI: https://doi.org/10.22034/abec.2024.711550

[14] Susai, R., Al-Hashem, A., Krishnaveni, A., et al., 2024. Corrosion Inhibition by Fruit Extracts-Inhibition of Corrosion of Mild Steel in Simulated Concrete Pore Solution Prepared in Sea Water by an Aqueous Extract of Apple Juice—A Case Study. Zastita Materijala. 65(1), 22–34. DOI: https://doi.org/10.62638/ZasMat1040

[15] Jeslina, V., Kirubavathy, S.J., Al-Hashem, A., et al., 2023. Mild Steel Corrosion Inhibition in 1 M HCl by an Alcoholic Extract of Sargassum muticum. Portugaliae Electrochimica Acta. 41, 151–165. DOI: https://doi.org/10.4152/pea.2023410204

[16] Krishnaveni, A., Anitha, N., Velkannan, V., et al., 2022. Inhibition of Corrosion of L 80 Alloy Pipeline Carrying Simulated Oil Well Water by Succinic Acid. Zastita Materijala. 63(4), 454–462. DOI: https://doi.org/10.5937/zasmat2204454K

[17] Sasilatha, T., Santhammal, R.S., Al-Hashem, A.H., et al., 2022. Inhibition of Corrosion of Mild Steel Hull Plates Immersed in Natural Sea Water by Sandalwood Oil Extract of Some Natural Products. Zastita Materijala. 63(1), 23–36. DOI: https://doi.org/10.5937/zasmat2201023R

[18] Karahacane, H., Khadraoui, A., Hachama, K., et al., 2026. Investigation of the Corrosion Inhibitory Effect of Melissa officinalis Ethanolic Extract on API 5L X70 Steel in Hydrochloric Acid. Journal of Bio- and Tribo-Corrosion. 12(2), 62. DOI: https://doi.org/10.1007/s40735-026-01124-x

[19] Khadraoui, A., Khelifa, A., Boutoumi, H., et al., 2014. Mentha pulegium Extract as a Natural Product for the Inhibition of Corrosion. Part I: Electrochemical Studies. Natural Product Research. 28(15), 1206–1209. DOI: https://doi.org/10.1080/14786419.2014.919288

[20] Khadraoui, A., Khelifa, A., Hachama, K., et al., 2015. Synergistic Effect of Potassium Iodide in Controlling the Corrosion of Steel in Acid Medium by Mentha pulegium Extract. Research on Chemical Intermediates. 41(10), 7973–7980. DOI: https://doi.org/10.1007/s11164-014-1870-8

[21] Benghalia, M.A., Fares, C., Khadraoui, A., et al., 2018. Performance Evaluation of a Natural and Synthetic Compound as Corrosion Inhibitors of API 5L X52 Steel in Hydrochloric Acid Media. Moroccan Journal of Chemistry. 6(1), 51–61.

[22] Benghalia, M.A., Fares, C., Khadraoui, A., et al., 2019. Assessment of Corrosion Inhibitory Effect of Ruta chalepensis Flavonoid Extracts on API 5L X52 Steel in 1 M HCl Medium. Environmental Engineering and Management Journal. 18(9), 2009–2021. DOI: https://doi.org/10.30638/eemj.2019.191

[23] Nashed, O., Talib, N.K., Lal, B., et al., 2023. Measurement of physicochemical properties of green aqueous amino acid‐based ionic liquids and their correlation with temperature and concentration. Asia‐Pacific Journal of Chemical Engineering. 18(2), e2860. DOI: https://doi.org/10.1002/apj.2860

[24] Akalezi, C.O., Oguzie, E.E., Ogukwe, C.E., et al., 2015. Rothmannia longiflora extract as corrosion inhibitor for mild steel in acidic media. International Journal of Industrial Chemistry. 6(4), 273–284. DOI: https://doi.org/10.1007/s40090-015-0050-z

[25] Chidiebere, M.A., Ogukwe, C.E., Oguzie, K.L., et al., 2012. Corrosion inhibition and adsorption behavior of Punica granatum extract on mild steel in acidic environments: Experimental and theoretical studies. Industrial & Engineering Chemistry Research. 51(2), 668–677.

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How to Cite

Abdlmanam S. A. Elmaryami, Omar Nashed, Mahmoulah Y. Abdulraheem, Abdul Hamid Omran Saleh, Salah Mohamed Sallab, Garrett Arciete, & Rahel G. Rahel. (2026). Investigation on Ficus carica and Punica granatum Extracts as Eco-Friendly Corrosion Inhibitors for C1018 Carbon Steel in Acidic and Marine Environments. New Environmentally-Friendly Materials, 5(1), 27–39. https://doi.org/10.55121/nefm.v5i1.1249