A Proof of Concept Zinc-Mediated RDRP of Alanine Acrylamide for Efficient Dye Encapsulation to Clean the Wastewater for Green Environment
DOI:
https://doi.org/10.55121/nefm.v3i1.297Keywords:
Amino Acid, Smart Polymer, Biohybrid, PH-Responsive, Dye EncapsulationsAbstract
A PH-responsive synthetic biohybrid biohybrid module poly (L-alanine acrylamide)-blockpoly(methylmethacrylate (PAAla-b-PMMA) diblock biohybrids, based on hydrophilic PAAla and hydrophobic PMAA segments, is developed via direct switching from Zinc (Zn) catalyst polymerization. EbiB was used as an initiator to Zn-mediate Reversible deactivation radical polymerization (RDRP) of alanine-derived monomer, Alanine acrylamide (AAla), yielding a series of (PAAla-b-PMAA)-The copolymer’s stimuli response has been assessed against pH. The aim of this investigation was to translate this structure into a synthetic polymer. The block-copolymer is capable of removal of toxic dye from wastewater. The produced polymer has remarkable adsorption capabilities towards a range of synthetic dyes, providing viable options for wastewater treatment that is sustainable. By using this creative approach, this research offer a practical and environmentally friendly way to deal with one of the most enduring environmental problems: dye contamination-induced water pollution. The study also looks at how this RDRP approach may be scaled up for industrial applications, guaranteeing a major decrease in environmental toxicity and encouraging the creation of
environmentally friendly wastewater management solutions. This approach not only enhances the effectiveness of dye removal but also contributes to the development of eco-friendly and recyclable materials for wastewater purification for green environment.
References
[1] Corrigan, N., Jung, K., Moad, G., et al., 2020. Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications. Progress in Polymer Science. 111, 101311. DOI: https://doi.org/10.1016/j.progpolymsci.2020.101311
[2] Scholten, P.B., Moatsou, D., Detrembleur, C., et al., 2020. Progress toward sustainable reversible deactivation radical polymerization. Macromolecular rapid communications. 41(16), 2000266. DOI: https://doi.org/10.1002/marc.202000266
[3] Bagheri, A., Fellows, C.M., Boyer, C., 2021. Reversible deactivation radical polymerization: from polymer network synthesis to 3D printing. Advanced Science. 8(5), 2003701. DOI: https://doi.org/10.1002/advs.202003701
[4] Moad, G., 2023. Living and controlled reversible‐activation polymerization (RAP) on the way to reversible‐deactivation radical polymerization (RDRP). Polymer International. 72(10), 861–868. DOI: https://doi.org/10.1002/pi.6552
[5] Matyjaszewski, K., 2012. Atom transfer radical polymerization (ATRP): current status and future perspectives. Macromolecules. 45(10), 4015–4039. DOI: https://doi.org/10.1021/ma3001719
[6] Anastasaki, A., Nikolaou, V., Nurumbetov, G., et al., 2016. Cu (0)-mediated living radical polymerization: a versatile tool for materials synthesis. Chemical reviews. 116(3), 835–877. DOI: https://doi.org/10.1021/acs.chemrev.5b00191
[7] Lligadas, G., Grama, S., Percec, V., 2017. Single-electron transfer living radical polymerization platform to practice, develop, and invent. Biomacromolecules. 18(10), 2981–3008. DOI: https://doi.org/10.1021/acs.biomac.7b01131
[8] Nurumbetov, G., Engelis, N., Godfrey, J., et al., 2017. Methacrylic block copolymers by sulfur free RAFT (SF RAFT) free radical emulsion polymerisation. Polymer Chemistry. 8(6), 1084–1094. DOI: https://doi.org/10.1039/C6PY02038K
[9] Rosen, B.M., Jiang, X., Wilson, C.J., et al., 2009. The disproportionation of Cu (I) X mediated by ligand and solvent into Cu (0) and Cu (II) X2 and its implications for SET‐LRP. Journal of Polymer Science Part A: Polymer Chemistry. 47(21), 5606–5628. DOI: https://doi.org/10.1002/pola.23690
[10] Wang, J.-S., Matyjaszewski, K., 1995. " Living"/controlled radical polymerization. Transition-metal-catalyzed atom transfer radical polymerization in the presence of a conventional radical initiator. Macromolecules. 28(22), 7572–7573. DOI: https://doi.org/10.1021/ma00126a041
[11] Gromada, J., Matyjaszewski, K., 2001. Simultaneous reverse and normal initiation in atom transfer radical polymerization. Macromolecules. 34(22), 7664–7671. DOI: https://doi.org/10.1021/ma010864k
[12] Min, K., Jakubowski, W., Matyjaszewski, K., 2006. AGET ATRP in the presence of air in miniemulsion and in bulk. Macromolecular rapid communications. 27(8), 594–598. DOI: https://doi.org/10.1002/marc.200600060
[13] Min, K., Gao, H., Matyjaszewski, K., 2006. Development of an ab initio emulsion atom transfer radical polymerization: from microemulsion to emulsion. Journal of the American Chemical Society. 128(32), 10521–10526. DOI: https://doi.org/10.1021/ja0629054
[14] Matyjaszewski, K., Coca, S., Gaynor, S.G., et al., 1997. Zerovalent metals in controlled/“living” radical polymerization. Macromolecules. 30(23), 7348–7350. DOI: https://doi.org/10.1021/ma971258l
[15] Percec, V., Guliashvili, T., Ladislaw, J.S., et al., 2006. Ultrafast synthesis of ultrahigh molar mass polymers by metal-catalyzed living radical polymerization of acrylates, methacrylates, and vinyl chloride mediated by SET at 25 C. Journal of the American Chemical Society. 128(43), 14156–14165. DOI: https://doi.org/10.1021/ja065484z
[16] Zhang, Y., Wang, Y., Matyjaszewski, K., 2011. ATRP of methyl acrylate with metallic zinc, magnesium, and iron as reducing agents and supplemental activators. Macromolecules. 44(4), 683–685. DOI: https://doi.org/10.1021/ma102492c
[17] Chung, I.-D., Britt, P., Xie, D., et al., 2005. Synthesis of amino acid-based polymers via atom transfer radical polymerization in aqueous media at ambient temperature. Chemical Communications. (8), 1046–1048. DOI: https://doi.org/10.1039/B416591H
[18] Ayres, L., Adams, P.H.H., Löwik, D.W., et al., 2005. β-sheet side chain polymers synthesized by atom-transfer radical polymerization. Biomacromolecules. 6(2), 825–831. DOI: https://doi.org/10.1021/bm049421p
[19] Rafiee, Z., 2016. Controlled radical polymerization of an acrylamide containing l-alanine moiety via ATRP. Amino acids. 48(2), 437–443. DOI: https://doi.org/10.1007/s00726-015-2097-8
[20] Rupert, B.L., Mulvihill, M.J., Arnold, J., 2006. Atom-transfer radical polymerization on zinc oxide nanowires. Chemistry of materials. 18(21), 5045–5051. DOI: https://doi.org/10.1021/cm061387t
[21] Ng, G., Jung, K., Li, J., et al., 2021. Screening RAFT agents and photocatalysts to mediate PET-RAFT polymerization using a high throughput approach. Polymer Chemistry. 12(45), 6548–6560. DOI: https://doi.org/10.1039/D1PY01258D
[22] Dadashi‐Silab, S., Atilla Tasdelen, M., Mohamed Asiri, A., et al., 2014. Photoinduced atom transfer radical polymerization using semiconductor nanoparticles. Macromolecular rapid communications. 35(4), 454–459. DOI: https://doi.org/10.1002/marc.201300704
[23] Mori, H., Matsuyama, M., Endo, T., 2008. Physics. Assembled structures and chiroptical properties of amphiphilic block copolymers synthesized by RAFT polymerization of N‐acryloyl‐L‐alanine [in Japanese]. Macromolecular Chemistry and Physics. 209(20), 2100–2112. DOI: https://doi.org/10.1002/macp.200800254
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